Explain how vacancies are introduced in an ionic solid when a cation of higher Chapter 1: the Solid State Chemistry Class 12 solutions are developed for assisting understudies with working on their score and increase knowledge of the subjects. Question 1.21: Explain how vacancies are introduced in an ionic solid when a cation of higher valence is added as an impurity in it. is solved by our expert teachers. You can get ncert solutions and notes for class 12 chapter 1 absolutely free. NCERT Solutions for class 12 Chemistry Chapter 1: the Solid State is very essencial for getting good marks in CBSE Board examinations
Question 1.21: Explain how vacancies are introduced in an ionic solid when a cation of higher valence is added as an impurity in it.
Answer
When a cation of higher valence is added as impurity in an ionic solid . two or more than two cations of lower valances is replace by less than 2 ions of higher valances . To maintain the electrical neutrality few sites become vacant.
For example,
Sr2+ is added to NaCl, each Sr2+ ion replaces two Na+ ions. Because the charge on 1 ions of Sr2+ is equal to charge on two ions of Na+. and One Na+ ions leave there site
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